Chemistry

Alkynes

  1. Alkynes have a triple bond
  2. Examples of Alkynes are Butyne or Propyne

Cyclical Compounds and Halides

  1. Cyclic Aliphatics are ring chemicals
  2. Examples are Cyclobutane or Methyl Cyclopentane

Benzene

  1. Benzene molecules are rings with alternating double bonds.
  2. Sometimes called aromatics because they tend to smell.
  3. f a benzene ring acs as a branch it’s a phenyl, eg. phenyl butane or 2-methy 3-phenyl butane

Alcohols

  1. Alcohols contain an OH group.
  2. This usually makes them polar creating strong intramolecular hydrogen bonds so they have much higher melting and boiling points.
  3. A Primary Alcohol has the OH group at the end of the molecule.
  4. A Secondary Alcohol has the OH chain as a branch. The carbons either side are often referred to as R for Rest.
  5. A Tertiary Alcohol is a secondary alcohol which has another group attached to the same carbon as the OH.

Carboxylic Acids

  1. Carboxylic acids have the Carboxylic acid functional group at the end
  2. End in -oic acid, eg Methanoic Acid.
  3. Methanoic Acid is otherwise known as Formic Acid
  4. Ethanoic Acid is otherwise known as Acetic Acid

Esters

  1. Made from Acohols and carboxylic acids
  2. eg Ethyl Methanoate

Ketones, Aldehydes, Ethers and Amines

  1. An Aldehyde has a double bonded Oxygen at the end of the Carbon chain
  2. Ketones have a double bonded Oxygen side group at a position other than the end of the carbon chain.
  3. Ketones have -one at the end of them, eg Butanone
  4. Ethers have an Oxygen in the middle of the carbon chain, eg Methyethylether
  5. An Amine has an NH2 side group. Eg. Amino Ethane.

Organic Chemistry Song

Redox (Reduction Oxidation) Reactions

  1. Oxidation is the loss of electrons.
  2. Reduction is the gain of electrons (reduction in charge)
  3. An oxidising agent gains electrons and so causes oxidation. Oxygen is an Oxidising agent as it can compete it’s outer shell by gaining two electrons.

Moles

  1. A Mole is 6.02 x 1023 atoms or molecules. This is Avogadro’s constant
  2. A Mole’s weight in grams is equal to it’s atomic weight in AMUs.
  3. One mole of water is a small ice cube.
  4. One mole of peas would cover 25 planets the size of earth to a depth of one meter.


Naming Simple Organic Compounds

Fischer and Haworth Projections

Note the following molecular diagrams are NOT equivalent.

Fischer projections

  1. Generaly represent all the atoms
  2. use lines to represent bonds

eg.

D-glucose_Fischer

see http://en.wikipedia.org/wiki/Haworth_projection for more.

Haworth Projections

  1. Visualise the molecule in three dimentions so more commonly used for ring molecules.
  2. Carbon and Hydrogen atoms are assumed and are not drawn

eg

Glucose_Haworth

See http://en.wikipedia.org/wiki/Haworth_projection for more detail.

This image is used under the Creative Commons Attribution ShareAlike 3.0 License.

What is Equilibrium

  1. Reactions move in both directions.
  2. Equilibrium is the point at which the rate of forward reaction is equal to the rate of reverse reaction.

The Equilibrium Constant & Expression

The equilibrium expression is a ratio between the product and the reactant.

eg. for H2 + I2 <=> 2HI

The Equilibrium expression represents tre final ratio between the two:

[HI]2 / [H2][I2]

Heterogeneous Equilibrium

Effects of Temperature on Equilibrium

  1. If temperature increases the reaction will shift in the endothermic direction (taking in heat).
  2. If temperature decreases the reaction will shift in the exothermic direction.

Chiral Carbon

A Chiral Carbon is one which does not exhibit symmetry. For more information and a test see:

http://www2.vuw.ac.nz/staff/paul_teesdale-spittle/organic/chiral_web/main.htm

Kinetics

Rate Law and Orders of Reaction

  1. The order of a reaction determines how much faster the reaction will go if the concentration of reactant is increased
  2. Rate = K[CO2]n

Stepwise Ionic Bonding